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Description

GA931005: Fmoc-Thr((Ac)7-Cel-β-D)-OHC45H53NO23 959. 9 An Fmoc protected L threonine building block carrying a D cellobiose (Glc1 4Glc) disaccharide, designed for solid phase peptide synthesis (SPPS) of glycopeptides. The N Fmoc group is removed under standard base conditions (piperidine) during chain elongation, while the free carboxylic acid is available for coupling to the growing resin bound peptide. The sugar hydroxyl groups are protected as seven acetate esters (Ac7), which keep

/ Fmoc-Tyr(Glc(Ac)4-β-D)-OH / N-α-(9-Fluorenylmethyloxycarbonyl)-O-(2

C29H44D6O2 / 436

19 / IgA1 synthetic Hinge Region peptide fragment from Val222 to Ser240 with glycosylation (α-GalNAc) at Thr228

α-D-Man-Bu-CO2H

12 / An Fmoc-protected L-serine building block carrying a Neu5Acα2-6GalNAcα disaccharide

/ α-D-Man-Ethyl-Azide / α-Man-Et-N3

Synthetic MUC-1 (tri-STn) glycopeptide

which is yellow under basic conditions (absorbance maximum ~405 nm)

27 / An α-D-mannose ligand equipped with a terminal carboxylic acid through a short butyl spacer

/ Fmoc-Ser(Glc(Ac)4-α-D)-OH / N/A

99 / Muc5AC (UniProt ID P98088) is a gel-forming glycoprotein produced by the goblet cells in the tracheobronchial surface epithelium

/ H-Ser(Gal(β(1-3)GalNAc)-OH / TF Epitope (Serine)